accelerating the discovery and in-depth understanding of photocatalysts and photoactive material for solar-driven co2 reduction reaction.

The research in Thrust 2 involves the following themes:

  • Use of experiment and theory to accelerate the identification of semiconductor materials with appropriate band energetics for efficient photocatalysis.
  • Development and characterization of materials for protection of light absorbers to achieve robust photocatalysis with large photovoltage.
  • Understanding and control of catalytic activity and selectivity at the surfaces of photoactive materials.
  • Design of photonic motifs to enhance light harvesting and photocatalysis.

Thrust 2 Coordinator is Dr. John Gregoire


Selected Recent Publications

Brown, A. M. et al. Experimental and Ab Initio Ultrafast Carrier Dynamics in Plasmonic Nanoparticles. Physical Review Letters, 118 (8), 087401, DOI: 10.1103/PhysRevLett.118.087401 (2017).

Jiang, C.-M., Farmand, M., Wu, C., Liu, Y.-S., Guo, J., Drisdell, W.S., Cooper, J. K., and Sharp, I. D. Electronic Structure, Optoelectronic Properties, and Photoelectrochemical Characteristics of γ-Cu3V2O8 Thin Films. Chemistry of Materials, DOI: 10.1021/acs.chemmater.7b00807 (2017).

Newhouse, P. F., Reyes-Lillo, S. E., Li, G., Zhou, L., Shinde, A., Guevarra, D., Suram, S. K., Soedarmadji, E., Richetr, M. H., Qu, X., Persson, K., Neaton, J. B., Gregoire, J. M. Discovery and Characterization of a Pourbaix Stable, 1.8 eV Direct Gap Bismuth Manganate Photoanode. Chem. Mater, DOI: 10.1021/acs.chemmater.7b03591 (2017).

Omelchenko, S. T. et al. Excitonic Effects in Emerging Photovoltaic Materials: A Case Study in Cu2O. ACS Energy Letters, DOI: 10.1021/acsenergylett.6b00704 (2017).

Yan, Q. et al. Solar fuels photoanode materials discovery by integrating high-throughput theory and experiment. Proceedings of the National Academy of Sciences, DOI: 10.1073/pnas.1619940114 (2017).

Segev, G., Jiang, C.-M., Cooper, J. K., Eichorn, J., Toma, F., Sharp, I. D. Quantification of the loss mechanisms in emerging water splitting photoanodes through empirical extraction of the spatial charge collection efficiency. Energy&Environmental Science, DOI: 10.1039/C7EE03486E (2018).

For complete list of JCAP work, please see publications and research highlight pages.